機能性グラフェンを用いた電子移動速度、活性、選択性の優れた光触媒の開発
【研究分野】環境技術・環境負荷低減
【研究キーワード】
Ag3PO4 crystals / graphene / photocatalyst / visible-light-driven / graphene oxide / dispersion / stabilization / centrifugation / exfoliation
【研究成果の概要】
We report on a novel yet facile approach to the mass production of photocatalytic Ag3PO4 particles by using graphene oxide (GO) sheets as templates. GO was first stabilized with poly(diallyldimethylammonium chloride), a poly-cationic electrolyte, Ag3PO4 crystals of submicro-size and with rhombic dodecahedron and tetrahedral morphologies were then synthesized over the GO sheets by using Ag(NH3)2+ and H2PO4- as the starting materials via precipitation reactions. After a desirable UV irradiation treatment, Ag3PO4 was partially reduced to Ag0 and GO to graphene; tetrahedral crystals consisted of Ag, Ag3PO4 and graphene were obtained. The Ag/Ag3PO4/graphene combinational nanostructures are highly transparent and moreover, showing high visible-light-driven photocatalytic activities. Photodegradation studies with acridine orange (AO) as the targeted chemicals gave better results than TiO2 (P25), WO3, and the sole Ag/Ag3PO4, demonstrating the high applicability of the Ag/Ag3PO4/graphene combinational photocatalyst.
【研究代表者】
【研究種目】特別研究員奨励費
【研究期間】2015-04-24 - 2017-03-31
【配分額】2,400千円 (直接経費: 2,400千円)